Just line the two remotes up head to head a few inches apart and follow the directions in the programming manual (if you don't have it, download it from hometheatermaster.com). With the exception of Volume and Channel Up/Down commands, a single push of the button on the remote you're learning from is all you need.
If you have any other questions, you'd be better off to post them in the "Home Theater Master" forum.
Mike
www.SurfRemote.com