I think as a combo of likes and ones to really
show DVD medium: (not necessarily in order of
best)

1. Die Hard I (5 Star Collection)

2. The Fifth Element (Superbit)

3. Starship Troopers (Superbit)

4. The Lion King

5. Fight Club (2-disc)

Others:

6. A Bug's Life (2-disc Collector's)

7. LOTR: Fellowship of the Ring

8. Alien Quadrilogy (though haven't seen it all
yet)

9. Daredevil (really amazing visual and sound)

10. Die Another Day (also really amazing visuals
and sound)